Here is the link for the preparation guide for Exam 70-562 TS: .NET Framework 3.5, ASP.Net Application Development.

The skills being measured includes:

1. Configuring and Deploying Web Applications (10 percent)
2. Consuming and Creating Server Controls (20 percent)
3. Working with Data and Services (17 percent)
4. Troubleshooting and Debugging Web Applications (16 percent)
5. Working with ASP.NET AJAX and Client-Side Scripting (15 percent)
6. Targeting Mobile Devices (5 percent)
7. Programming Web Applications (17 percent)

source : http://www.microsoft.com/learning/mcpexams/status/examstoretire.mspx 

Developer exams
• Exam 70-300: Analyzing Requirements and Defining Microsoft .NET Solution Architectures
• Exam 70-301: Managing, Organizing, and Delivering IT Projects by Using Microsoft Solutions Framework 3.0
• Exam 70-305: Developing and Implementing Web Applications with Microsoft Visual Basic .NET and Microsoft Visual Studio .NET
• Exam 70-306: Developing and Implementing Windows-based Applications with Microsoft Visual Basic .NET and Microsoft Visual Studio .NET
• Exam 70-310: Developing XML Web Services and Server Components with Microsoft Visual Basic .NET and the Microsoft .NET Framework
• Exam 70-315: Developing and Implementing Web Applications with Microsoft Visual C# .NET and Microsoft Visual Studio .NET
• Exam 70-316: Developing and Implementing Windows-based Applications with Microsoft Visual C# .NET and Microsoft Visual Studio .NET
• Exam 70-320: Developing XML Web Services and Server Components with Microsoft Visual C# and the Microsoft .NET Framework
• Exam 70-330: Implementing Security for Applications with Microsoft Visual Basic .NET
• Exam 70-340: Implementing Security for Applications with Microsoft Visual C# .NET

Microsoft SQL Server exams
• Exam 70-228: Installing, Configuring, and Administering Microsoft SQL Server 2000 Enterprise Edition
• Exam 70-229: Designing and Implementing Databases with Microsoft SQL Server 2000 Enterprise Edition